To add a payment from a bank account to an expense, click on the expense in your Expenses tab and then click 'Add payment':

You will then be able to choose the relevant account.

For a manual account, you'll be able to adjust the amount paid (in case of partial payment, for example).

If you select a bank account for which the transactions have been imported, you'll see a list of suggested transactions and can click on the appropriate one to apply it to the expense.

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